Journal of Oral Science Research ›› 2020, Vol. 36 ›› Issue (9): 879-884.DOI: 10.13701/j.cnki.kqyxyj.2020.09.018

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Effects of Aromatic Amino Acids on Growth, Fluorescence, and Color Properties of Hydroxyapatite

ZHANG Kainan1, GUO Yaru1, CAI Xinjie1,2, JIANG Tao1,2*, WANG Yining1,2*   

  1. 1. The State Key Laboratory Breeding Base of Basic Science of Stomatology (Hubei-MOST) & Key Laboratory of Oral Biomedicine Ministry of Education, School of Stomatology, Wuhan University, Wuhan 430079, China;
    2. Department of Prosthodontics. Stomatological Hospital, Wuhan University, Wuhan 430079, China
  • Received:2020-01-06 Online:2020-09-28 Published:2020-09-15

Abstract: Objective: To study the effects of three aromatic amino acids (AAA) on the growth, color, and fluorescence characteristics of hydroxyapatite (HA) crystals, and to provide ideas for the development of dental color materials. Methods: The hydrothermal method was used to synthesize HA and AAA complex (HA-AAA) as test group. X-ray diffraction (XRD), Fourier infrared spectroscopy (FTIR), ultraviolet spectrophotometer (UV), color, Raman, and DIAGNOdent were used to detect the sample. Pure HA samples were synthesized in the same way as control group. The crystallinity index (CI), relative carbonate content (RCC), whiteness value W*, Raman relative intensity (RRI), laser-induced fluorescence intensity (FI), full height at half maximum (FWHM), and DD value of DIAGNOdent were calculated and analyzed. Results: The CI and RRC values of HA-AAA were significantly lower than those of the test group, and the W*, FI, and DD values were statistically different from those of the control group. Conclusion: AAA can inhibit the growth of HA crystals, and significantly deepen the HA color and enhance the laser-induced fluorescence.

Key words: aromatic amino acid, hydroxyapatite, crystal size, color, fluorescence